A semi-auto made entirely of ceramics and polymers would be technically possible, but it would be a nightmare to actually make, probably would not function reliably and would have a very limited lifespan. Not to mention when it failed it would probably explode. But other than that, a piece of cake!
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A ceramic knife is a hell of a lot simpler than a ceramic/polymer gun (the ancient Mayans had obsidian glass knives). Now a single shot, derringer or pepperbox design would be much easier than a revolver or semi-auto. Doable, but I would not want to be shooting it.
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